An on-demand distributed clustering algorithm based on neural network was proposed. The system parameters and the combined weight for each node were computed, and cluster-heads were chosen using the weighted clustering algorithm, then a training set was created and a neural network was trained. In this algorithm, several system parameters were taken into account, such as the ideal node-degree, the transmission power, the mobility and the battery power of the nodes. The algorithm can be used directly to test whether a node is a cluster-head or not. Moreover, the clusters recreation can be speeded up.