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通过分析传统ATRP(原子转移自由基聚合)体系的不足之处,指出在原有ATRP的基础上引入的电子转移技术[即电子转移生成催化剂的ATRP(AGET ATRP)]的必要性。概括了AGET ATRP的类型[包括电子转移活化再生催化剂引发的ATRP(ARGET ATRP)、活化剂连续再生引发剂引发的ATRP(ICAR ATRP)、生物还原剂还原的ATRP、电化学介导的ATRP(eATRP)和终极ATRP(Ultimate ATRP)等],并讨论了AGET ATRP的影响因素、过程机制。最后对AGET ATRP的研究方面进行了展望。
By analyzing the shortcomings of the traditional ATRP (Atom Transfer Radical Polymerization) system, the necessity of introducing electron transfer technology [ie, ATRP (Electron Transfer Catalyst) for the generation of ATRP based on the original ATRP] is pointed out. The types of AGET ATRP [including ATRP (ARGET ATRP) initiated by electron transfer activated regeneration catalyst, ATRP (ICAR ATRP) triggered by activator continuous regenerative initiator, ATRP reduced with bioreduct, electrochemically mediated ATRP ) And the Ultimate ATRP (Ultimate ATRP), etc.], and discussed the AGET ATRP influencing factors, process mechanism. Finally, the research on AGET ATRP is prospected.