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本文是作者在钼原子簇合成化学研究的综合性报导，包括自兜合成和设计合成两个部分。这一部分概述了一些Ｍｏ（＋３）～Ｍｏ（＋６）单核化合物在Ｃｌ~－、Ｓ~（２－）、ＣＨ_３ＣＯ_２~－和（ＥｔＯ）ＰＳ_２~－等配基参与下的自兜反应及其产物，总结了成簇的某些规律。包括Ｍｏ原子的价态，μ－桥基的种类，介质的酸度对所形成的簇合物的影响。反应中卤原子的交换现象，以及和ＲＣＯ_２~－（ＥｔＯ）_２ＰＳ_２~－两种双齿配基的配位特点。讨论了自兜合成方法的局限性。
This article is a comprehensive review of the chemistry of molybdenum cluster synthesis by authors, including the synthesis of self-pockets and the design and synthesis of two parts. This section summarizes the self-pocket reaction of some Mo (+3) ~ Mo (+6) mononuclear compounds with the participation of the ligands Cl ~ -, S ~ (2 -), CH_3CO_2 ~ - and (EtO) The product, summarizes some of the laws of clustering. Including the valence of Mo atoms, the type of μ-bridge and the acidity of the medium on the clusters formed. The exchange phenomenon of halogen atoms in the reaction, and the coordination characteristic with two bidentate ligands of RCO_2 ~ - (EtO) _2PS_2 ~ -. Discuss the limitations of the self-pouch synthesis method.