Synthesis and Crystal Structure of a Novel Organic Adduct Nonlinear Optical Material: 3,5-Dinitroben

来源 :结构化学 | 被引量 : 0次 | 上传用户:wangqin613117
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
The title compound (C2H7NO·C7H4N2O6) has been obtained by the reaction of etha- nolamine with 3,5-dinitrobenzoic acid in deionized water at room temperature. The crystal crystal- lizes in orthorhombic, space group P212121 with a = 6.048(2), b = 9.146(3), c = 21.955(7)(A), C9H11N3O7, Mr = 273.21, Z = 4, V = 1214.3(7)(A)3, Dc = 1.494 g/cm3, F(000) = 568, μ(MoKα) = 0.131 mm-1, R1 = 0.0338 and wR2 = 0.0497. The new organic adduct is composed of one ethanolamine and one 3,5-dinitrobenzoic acid, which are linked up by O-H…O and N-H…O types of hydrogen bonds to form a nine-membered ring and an eleven-membered ring, extending into a one-dimensional network structure.
其他文献
Intramolecular cyclization of β -methyl substituted epoxide under aprotics (e.g. LDA in benzene) and protic conditions (e.g. LiOH in MeOH/H2O)both gave a mixtu
A series of noble metal catalysts (Ru, Rh, Ir, Pt, and Pd) supported on alumina-stabilized magnesia (Spinel) were used to produce syngas by methane reforming wi
In this article, the author studies the mechanism of formation of necrotic cores in the growth of tumors by using rigorous analysis of a mathematical model. The
Direct decomposition of methane was carried out using a fixed-bed reactor at 700 ℃ for the production of COx-free hydrogen and carbon nanofibers. The catalytic
From the κ symmetric action of ⅡB string in AdS2 × S2 background given by Zhou, we derive the equations of motion. By using the twisted dual transformation w
In this paper, we find the invariant eigen-operators (IEOs) and the energy-level gap of a system with a two-level atom interacting with single mode cavity field
Two new dihydroflavonoids were obtained from the traditional Chinese medicinal herb Patrinia villosa Juss. Their structures were elucidated as (2S)-5, 7, 2′, 6
在CCSD(T)/6-311g(d,p)/B3LYP/6-311g(d,p)的基础上对F原子与反式的1,3-丁二烯的反应体系进行了理论研究.计算中发现,这个反应体系有两个形成中间复合物的通道.同时,理论计算
The Maslov P-index theory for a symplectic path is defined. Various properties of this index theory such as homotopy invariant, symplectic additivity and the re
The reduced viscosity of polymer guar gum solutions containing a certain concentration of sodium dodecyl benzene sulfonate (SDBS) was measured. It has been foun