PRODUCTION, ISOLATION AND SPECTROSCOPIC STUDIES OF THE ENDOHEDRAL FULLERENE Sc_2@C_(80)(I-III)

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The isolation of multiple-isomers of Sc2@C80 (I, II, III) endohedral metallofullerenes is reported for the first time. The new C80-based Sc-metallofullerenes are characterized by UV-Vis-NIR absorption spectroscopy and detailed chromatographic retention time data. A close relationship between the isomer structure and the corresponding HPLC retention time of the metallofullerenes is presented. The isolation of multiple-isomers of Sc2 @ C80 (I, II, III) endohedral metallofullerenes is reported for the first time. The new C80-based Scfv metallofullerenes are characterized by UV-Vis-NIR absorption spectroscopy and detailed chromatographic retention time data A close relationship between the isomer structure and the corresponding HPLC retention time of the metallofullerenes is presented.
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