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本文阐述了导电高分子材料的概况,着重论述了结构型导电聚合物的导电机理——类似石墨的导电结构及孤子跳跃理论;叙述了聚乙炔的合成和结构、聚乙炔掺杂以及近年来新开拓的导电聚合物-聚荼、硅-酞菁聚合物及聚噻吩薄膜;介绍了这些结构型导电聚合物可应用于大功率的蓄电池、太阳能电池、电磁屏蔽材料以及电色材料等方面;最后指出当前导电高分子材料的发展方向——既要发展新的结构型导电聚合物又要确立切实的指导理论。
In this paper, the general situation of conductive polymer materials is introduced, and the conductive mechanism of conductive polymers - the conductive structure of graphite and soliton jump theory are emphatically discussed. The synthesis and structure of polyacetylene, doping of polyacetylene, Conductive polymer - Poly-Tu, Si-Phthalocyanine polymer and polythiophene films are introduced. These structural conductive polymers are introduced to high-power batteries, solar cells, electromagnetic shielding materials and electrochromic materials. Finally, Pointed out the development direction of the current conductive polymer materials - both the development of new structural conductive polymers and to establish practical guidance theory.