Electroless Plating of Ni-Fe-P Alloy and Corrosion Resistance of the Deposit

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Electroless Ni-Fe-P alloys in an alkaline bath were plated. The effects of deposition parameters on the plating rate and the coating composition were examined. The weight loss test and the anodic polarization measurement of the deposits in 3.5 wt pct NaCI solution (pH7.0) showed that the deposits with the mole ratio of NiS04/FeSO4 being 0.07:0.03, pH8.0 and 7.5 possess better corrosion resistance than that of the other deposits and the Ni-Fe-P deposits did not form passive films in this environment. In 5.0 wt pct NaOH solution, the Ni-Fe-P deposits have better corrosion resistance and formed passive films. The effects of deposition parameters on the plating rate and the coating composition were examined. The weight loss test and the anodic polarization measurement of the deposits in 3.5 wt pct NaCI solution (pH 7 .0) showed that the deposits with the mole ratio of NiS04 / FeSO4 being 0.07: 0.03, pH 8.0 and 7.5 possess better corrosion resistance than that of the other deposits and the Ni-Fe-P deposits did not form passive films in this environment. In 5.0 wt pct NaOH solution, the Ni-Fe-P deposits have better corrosion resistance and formed passive films.
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