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5. Zn/ ZrCl4 System Induced Reductive Cleavage of Se-Se Bond in Diaryl Diselenides: A Novel Method for

Zn/ ZrCl4 System Induced Reductive Cleavage of Se-Se Bond in Diaryl Diselenides: A Novel Method for

来源 :中国化学快报 | 被引量 : 0次 | 上传用户：tomjohn3168

【摘 要】

：

The Se-Se bond in diaryl diselenides was reduced by Zn/ZrCl4 system to produce selenide anions, which react with acyl chlorides or acid anhydrides to afford sel

【作 者】

：

Song Lin ZHANG Feng Shou TIAN 

【机 构】

：

College of Chemistry and Environmental Science

【出 处】

：

中国化学快报

【发表日期】

：

2004年期

【关键词】

：

Diselenides zinc zirconium (IV) chloride selenoesters 

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论文部分内容阅读

The Se-Se bond in diaryl diselenides was reduced by Zn/ZrCl4 system to produce selenide anions, which react with acyl chlorides or acid anhydrides to afford selenoesters in THF under mild and neutral conditions.

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