【摘 要】
：
A metal-organic coordination polymer,[Cd(C15H10N4)(C6H8O4)]2n (1,C15H10N4:2-methyl-pyrazino-[2,3-f][1,10]-phenanthroline (mpphen),C6H8O4: adipate),was synthesiz
【机 构】
：
Chemistry Department of Jilin Normal University
论文部分内容阅读
A metal-organic coordination polymer,[Cd(C15H10N4)(C6H8O4)]2n (1,C15H10N4:2-methyl-pyrazino-[2,3-f][1,10]-phenanthroline (mpphen),C6H8O4: adipate),was synthesized via hydrothermal synthesis.The polymer was characterized by elemental analysis,IR,TG and single-crystal X-ray diffraction.X-ray diffraction shows that 1 is a cadmium polymer constructed by adipate-bridged dinuclear clusters,and each adipate connects two clusters to form a two-dimensional planar structure.Crystal data for 1: monoclinic,space group C2/c,a = 22.403(9),b =16.039(6),c = 13.808(6) (A),β = 125.262(6)°,V = 4051(3) (A)3,Mr = 502.79,Dc= 1.649 g/cm3,μ(MoKα) = 1.114 mm-1,F(000) = 2016,Z= 8,the final R = 0.0509 and wR = 0.1054 for 1509observed reflections (I＞2σ(I)).
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