嵌段共聚物分子存在分子内相分离。如分子处于选择性溶剂中,不溶解的嵌段会收缩、聚集形成胶束。目前研究者对这种类型的胶束现象的兴趣集中在研究临界胶束浓度CMC和临界胶束温度CMT,胶束内聚集的共聚物分子数目N_m,胶束尺寸及建立理论模型等 Block copolymer molecules exist intramolecular phase separation. If the molecule is in a selective solvent, the insoluble blocks will contract and aggregate to form micelles. At present, researchers’ interest in this type of micelle phenomenon is focused on studying the critical micelle concentration CMC and the critical micelle temperature CMT, the number of cohesive molecules N_m aggregated within the micelle, the size of the micelles and establishing a theoretical model