Enhanced Photoelectrochemical Properties of Cu_2O-loaded Short TiO_2 Nanotube Array Electrode Prepar

来源 :Nano-Micro Letters | 被引量 : 0次 | 上传用户:dzbycp2009
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Copper and titanium remain relatively plentiful in earth crust.Therefore,using them in solar energy conversion technologies are of significant interest.In this work,cuprous oxide(Cu_2O)-modified short TiO_2 nanotube array electrode was prepared based on the following two design ideas:first,the short titania nanotubes obtained from sonoelectrochemical anodization possess excellent charge separation and transportation properties as well as desirable mechanical stability;second,the sonoelectrochemical deposition technique favours the improvement in the combination between Cu_2O and TiO_2 nanotubes,and favours the dispersion of Cu_2O particles.UV-Vis absorption and photo-electronchemical measurements proved that the Cu_2O coating extended the visible spectrum absorption and the solar spectrum-induced photocurrent response.Under AM1.5 irradiation,the photocurrent density of the composite electrode(i.e.sonoelectrochemical deposition for 5 min) was more than 4.75 times as high as the pure nanotube electrode.Comparing the photoactivity of the Cu_2O/TiO_2 electrode obtained using sonoelectrochemical deposition with others that synthesized using plain electrochemical deposition,the photocurrent density of the former electrode was ~2.2 times higher than that of the latter when biased at 1.0 V(vs.Ag/AgCl).The reproducible photocurrent response under intermittent illumination demonstrated the excellent stability of the composite electrode.Such kind of composite electrode material will have many potential applications in solar cell and other fields. Copper and titanium remain relatively plentiful in earth crust.Therefore, using them in solar energy conversion technologies are significant interest.In this work, cuprous oxide (Cu 2 O) -modified short TiO 2 nanotube array electrode was prepared based on the following two design ideas: first, the short titania nanotubes obtained from sonoelectrochemical anodization possess excellent charge separation and transportation properties as well as desirable mechanical stability; second, the sonoelectrochemical deposition technique favors the improvement in the combination between Cu_2O and TiO_2 nanotubes, and favors the dispersion of Cu_2O particles. UV-Vis absorption and photo-electron chemical measurements proved that the Cu 2 O coating extended the visible spectrum absorption and the solar spectrum-induced photocurrent response. Mnder AM 1.5 irradiation, the photocurrent density of the composite electrode (iesonoelectrochemical deposition for 5 min) was more than 4.75 times as high as the pure nan Comparing the photoactivity of the Cu 2 O / TiO 2 electrode obtained using sonoelectrochemical deposition with others that synthesized using plain electrochemical deposition, the photocurrent density of the former electrode was ~ 2.2 times higher than that of the latter when biquan at 1.0 V (vs. Ag / AgCl). The reproducible photocurrent response under intermittent illumination demonstrated the excellent stability of the composite electrode.Such kind of composite electrode material will have many potential applications in solar cell and other fields.
其他文献
你是否为孩子不够优秀而失落?你是否为该不该和孩子谈性而犹豫?你是否为不知怎样教孩子写作文而头疼?你是否为孩子的脆弱而忧虑?你是否为孩子过于内向而彷徨……那么不妨翻一
A novel soft polymer template containing a double-layer structure,which includes a thin layer of polymethylmethacrylate(PMMA)used as a pattern layer and a thick
南宁地区行政公署为贯彻执行广西区人民政府挂政发(1997)33号文精神。于1998年7月23日下发南署(1998)37号文对本地区小型多功能拖拉机管理工作作出规定:一、凡具备犁耙装置,并有烘
巴河之水滋养先生的血液五岳神州造就先生的躯体壮子之歌如向中华,响世界先生从沉梦中醒来一夜之间好一朵日月之花——中国荷花开遍香江,开遍渡江,开遍巴河开出雨后荷花映日红的
最近 ,烽火通信与陕西汉中电信签订了市话工程合同 ,为汉中地区电信市话网络提供GF2488 -01B设备。此外 ,烽火通信还与宝鸡电信签订了无线市话工程合同 ,这是烽火通信传输设备首次进入
We simulated the asymmetrical growth of cube-shaped nanoparticles by applying the Monte Carlo method.The influence of the specific mechanisms on the crystal gro
“乘法分配律”是北师大版四年级在探索规律学习中的一个重要的学习内容,这个内容是小学阶段运算教学重点也是教学难点。每次在进行这部分知识的教学时,总感觉这部分内容对学
中枢神经系统发生耐青霉素金黄色葡萄球菌(金葡菌)感染的发病率和死亡率都较高,新青霉素是治疗严重金葡菌感染的主要药物,但渗入脑脊液(CSF)的资料很少。新青Ⅰ治疗急性细菌性脑膜
1 概况 苏州河中段是指从中山西路3号桥至长寿路的河段,全长约8.3km,宽度为50~60m,平时水位一般不低于3m,属苏州河环境综合整治的中游段。该河段穿越了上海市区内的长宁、普
Eu~(3+)luminescence spectroscopy has been used to investigate the effective doping of alkoxide-based silica(SiO_2) gels using a novel pressure-assisted sol-gel