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用蓝细菌满江红鱼腥藻为吸附材料,研究了时间、pH、阳离子、阴离子等对水相中低浓度U(Ⅵ)的吸附影响。实验结果表明,满江红鱼腥藻对浓度低于5.5mg/L铀吸附迅速,平衡时间不超过2min;富集铀酰离子的最佳pH范围在5.0—8.5,铀酰离子可能以[UO2OH]+形式与藻细胞结合;Li+、Na+、K+、NH4+不与UO2+2竞争;Cu2+、Cd2+、Mn2+、Zn2+使满江红鱼腥藻的吸附容量下降;Cl-、SO2-4、NO-3不影响藻细胞对铀的吸附;经过简单串级,3.5‰—4.5‰鲜藻可将模拟废水中的铀从5.5mg/L降低至0.05mg/L。
Using cyanobacteria Azolla as the adsorptive material, the effects of time, pH, cation and anion on the adsorption of low concentration U (Ⅵ) in aqueous phase were studied. The results showed that Anabaena variabilis adsorbed uranium at a concentration lower than 5.5mg / L rapidly, and the equilibrium time was no more than 2min. The optimal pH range for enrichment of uranyl ion was 5.0-8.5, uranyl ion might The binding capacity of Cl-, SO2-4 and NO-3 to algae cells in the form of [UO2OH] + was higher than that of UO2 + 2, while that of Li2 +, Na +, K + and NH4 + The adsorption of uranium to algae cells was not affected. After a simple cascade, 3.5 ‰ -4.5 ‰ fresh algae could reduce uranium in simulated wastewater from 5.5 mg / L to 0.05 mg / L.