【摘 要】
：
不使用有机模板剂,采用超声化学法一步水解制得吸附硫酸根的介孔偏钛酸,500℃焙烧得到介孔SO2-4/TiO2固体超强酸.用XRD、TFEM、FTIR、低温氮吸附-脱附等手段对催化剂结构进行
【机 构】
：
安康学院化学化工系,上海工程技术大学材料工程学院
论文部分内容阅读
不使用有机模板剂,采用超声化学法一步水解制得吸附硫酸根的介孔偏钛酸,500℃焙烧得到介孔SO2-4/TiO2固体超强酸.用XRD、TFEM、FTIR、低温氮吸附-脱附等手段对催化剂结构进行了表征.结果表明,硫酸根在焙烧过程中与前驱体介孔偏钛酸孔壁上自由羟基的键合起到了孔结构导向及支撑作用,500℃焙烧后样品具有161 m2·g-1的比表面积及4.1 nm的平均孔径,酸强度H0介于-14.52与-16.02之间,硫含量为2.8%,晶型全部为锐钛矿相,介孔SO2-4/TiO2具有较大比表面、强酸特性和稳定性.催化合成富马酸二甲酯的最佳条件为:n(甲醇):n(富马酸)=6:1,催化剂用量为1.0%(反应物总质量),带水剂苯用量为10 mL,反应时间为3 h,催化剂重复使用7次,酯化率大于90%.
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