Interface enhanced well-dispersed Co9S8 nanocrystals as an efficient polysulfide host in lithium-sul

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The high specific capacity and energy density of lithium-sulfur batteries have attracted strong considerations on their fundamental mechanism and energy applications.However,polysulfide shuttle is still the key issue that impedes the development of Li-S batteries.Exploring nanocrystal hosts for polysulfide immobilization and conversion is a promising way.In this contribution,we have investigated well-dispersed Co9S8 nanocrystals grown on graphene oxide (GO) nanosheets with different degrees of dispersion as cathode host materials for Li-S batteries.The CogS8-GO composite with 1 wt% GO (GCS1) has an average crystal size of 76 nm and shows the strongest adsorption capability toward lithium polysulfides.When used as the host material for the cathode of Li-S batteries,the GCS1-sulfur composite exhibits an initial specific capacity of~1000 mAh g-1 at 0.5 C and shows an average decay rate of 0.11% for 500 cycles.This work on the dispersion control of Co9S8 nanocrystals may inspire more investigations on well-dispersed nanocrystal based hosts for Li-S batteries.
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