Change in Surface Microstrueture and Properties of PTFE after Solar Radiation and its Mechanism

来源 :武汉理工大学学报(材料科学版)(英文版) | 被引量 : 0次 | 上传用户:bleachff
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
A series of solar radiation tests for the polytetrafluoroethylene(PTFE) bulk and film samples were carried out using Q-SUN XE-3-HSC type Solar Radiation Simulator,with the test parameters as follows:radiation intensity is 1 120 W/m2,temperature is 55 ℃ and humidity is 70% RH.Surface morphology,composition and microstructure of the PTFE samples before and after radiation tests were characterized contrastively.Effect of solar radiation on the tribology and wetting properties of PTFE were also studied by tribometer and contact angle tester,respectively.The results show that,for radiated PTFE,surface roughness,the relative content of C element,the friction coefficients and the contact angle with water increased in varying degrees.In conclusion,the obvious change in PTFE samples can be mainly attributed to break of (CFx)-C bonds after bombardment of high energy UV photons,which causes the loss of F-rich groups,oxidation,crosslinking and restructuring of active unsaturated groups.
其他文献
A high-pressure hot-pressing process was applied to densify a commercial boron carbide-titanium diboride (B4C-TiB2) powder mixture. Nearly fully dense (98.6%) materials were obtained at 1700 ℃ under a pressure of 100 MPa. Compared to the sintering tempera
To elucidate the mechanism of brominated natural rubber (BNR),eight BNR samples with different bromine content were prepared from latex in different bromination time,and the microstructures were characterized by Fourier transform infrared spectroscopy (FT
Cement mortar with carbon fiber (CFc) and resin-cement mortar with carbon fiber (CFrc) were used as inner and outer cores of smart aggregate with Z shape, respectively, which was used as the basic perception units to prepare smart concrete aggregate with
Silicon carbide ceramics with different thicknesses/diameter ratios were prepared by using ultra-fine silicon carbide powder with the sintering additives of 1.0 wt% boron and 1.5 wt% carbon. The influence of thickness/diameter ratio on the microstructure
The titanium carbide phase was synthesized in laser melted-pool in situ as the reinforced particles of nickel based composite coating on Ti-6Al-4V alloy surface using the nickel and graphite blending powder by laser cladding. The microstructure investigat
Ag-modified TiO2 nanoflowers were prepared using a two-step process. The experimental process is green and free from contamination and can be synthesized directly at room temperature. Compared with pure TiO2, Ag-modified TiO2 enhances the absorption of vi
We introduced a parameter rs (the radius of the pores where the meniscus forms), which is composed of two factors, i e, water loss and cumulative pore size distribution (PSD), to provide a better explanation of the influence of superplasticizers(SPs) on e
Si/Cu3Si@C composites encapsulated in CNTs network (SCC-CNTs) were synthesized via the combination of ball-milling and CVD methods. SCC-CNTs consist of conductive Cu3Si, amorphous carbon layer, cross-linked CNTs, and the etched pores, which can play the s
A simple route to synthesize the polyaniline (PANI) nanofibers with diameter about 150 nm was reported.In this strategy,the PANI nanofibers were fabricated by electrochemical deposition by using two-electrode configuration in 0.01 M aniline and 0.01 M H2S