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对一系列+3和+4氧化态的单一和双一(环戊二烯)锕系和镧系元素络合物进行了 X 射线晶体结构研究。根据各种配合基的立体化学要求,分析了它们的配位几何学。这些研究清楚地指出:这些物质的结构和化学性质之间是强烈相关的。对很多新的化合物能作出配位几何学的合理而详细的预测。
X-ray crystallographic studies of a series of single and bis (cyclopentadienyl) actinide and lanthanide complexes in the +3 and +4 oxidation states were performed. According to the stereochemical requirements of various ligands, their coordination geometry was analyzed. These studies make it clear that there is a strong correlation between the structural and chemical properties of these substances. For many new compounds can make a reasonable and detailed prediction of coordination geometry.