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合成了模型化合物1,6-二-O-三苯甲基-D-甘露醇(TPMM),研究了它在混合溶剂中的高碘酸盐氧化反应的区选性。对氧化产物进行了分离鉴定。取得了最终氧化产物α-O-三苯甲基乙醛,制得了重要有机合成原料α-羟基乙醛。
The model compound 1,6-di-O-trityl-D-mannitol (TPMM) was synthesized and its regioselectivity for periodate oxidation in a mixed solvent was studied. The oxidation products were isolated and identified. Obtained the final oxidation product α-O-trityl acetaldehyde, has made an important organic synthesis of α-hydroxyacetaldehyde.