Determination of Mean Grain Size of Various Marbles from Turkey by Ultrasonic, Attenuation and Polar

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  Received: October 27, 2011 / Accepted: November 12, 2011 / Published: February 15, 2012.
  Abstract: The ultrasonic non-destructive testing technique continues to cover new materials at different test conditions, different testing techniques and higher accuracy, sensitivity and reliability. A detailed examination of the mechanical properties of various types of marble is attempted in the present experimental study with the aid of the non- destructive method of ultrasounds. In this work, 16 marble samples classified into three groups according to their formations have been studied to evaluate the grain size with ultrasonic methods. Ultrasonic velocity and attenuation values have been measured by using probes of 2 MHz and 4 MHz and their relationship with the grain sizes have been examined. It has been found that there is a linear relation between experimental and evaluated mean grain size in all marble groups.
  Key words: Marble, ultrasonic velocity, ultrasonic attenuation, mean grain size.
  The marbles having small grain size, dominant grain size distribution in a narrow range, and irregular grain boundary are more resistant against the ageing tests than the ones with large grain size, grain size distribution in a wide range, and straight grain boundary. Marble is no less complex; it is a product of metamorphism of limestone beds subjected to heat and/or pressure. It appears to be only anisotropic. Marble was extensively used for the construction of common buildings and the hardening of monuments and sculptures from ancient times. The very good physical and mechanical properties of marble, such as its high resistance to abrasion, translucence and capability to be polished, as well as its high strength and hardness render it one of the most widely used
   metamorphic minerals. They contain fossils, the preserved remains of ancient plants and animals. Sedimentary rocks are economically important since they can be used as construction material. The polarized microscopy images of studied sedimentary samples are shown in Fig. 2.
  2.1.2 Metamorphic Marble Samples
  Marble is generally a metamorphic rock resulting from regional or contact metamorphism of sedimentary carbonate rocks, either limestone or dolostone. This metamorphic process causes a complete recrystallization of the original rock into an interlocking mosaic of calcite and/or dolomite crystals. The temperatures and pressures necessary to form marble usually destroy any fossils and sedimentary textures present in the original rock. The sedimentary marble samples’ polarized microscopy images are given in Fig. 3.
  2.1.3 Travertine Marble Samples
  Travertine is a terrestrial sedimentary rock, formed by the precipitation of carbonate minerals from geo-thermally heated hot-springs. Travertine is often used as a building material. It is sometimes known as travertine limestone, sometimes as travertine marble; these are the same stone, even though it is neither
   by a Sonatest Sitescan 150 pulser/receiver instrument with Sonatest SLH2-10 and Sonatest SLH4-10 transducer operated at the frequency of 2 MHz-4MHz at the room temperature. Sonatest sonagel-W was used as interface between the transducers and marbles, given the smoothness of the marble surfaces. Velocities
  3.1 Experimental Works
  The mean values of the velocity, attenuation coefficient and rate of peak heights in the three types of marbles were given in Table 1 with mean grain size of samples.
  3.2 Reference Graphs
  In ultrasonic methods reference graphs have to be plotted to determine the mean grain size of samples. The reference graph could be plotted by two ways: the first way is to use reference sample and the second is to use different probes to carry out measurements from another region of sample. In this paper second way has been used to plot reference graph of samples because of anisotropic properties of marbles. The reference graph for the ultrasonic velocity method was plotted using the values from Table 1 as shown in Fig. 5.
  It can be seen from Fig. 5 that sedimentary marble
   The URA values of marble samples are shown in Fig. 7 which was plotted using the values from Table 1.
  The URA and ultrasonic attenuation methods depend on the rate of screen height of peaks. The main difference between these two methods is in URA method all the samples have to have the same thickness, but not in attenuation method. Because of this, correlation factors have the same range with attenuation method.
   3.3 Evaluation of Mean Grain Size
  In all methods fitting equations were used to evaluate the mean grain size of samples. Ultrasonic values have been measured 6 times using 4 MHz probe and the mean values have been used in calculations. The ultrasonic methods have been compared in the separate graphs for each marble group. Both ultrasonic measurement results obtained using 4 MHz probe and the evaluated mean grain size of samples were given in Table 2 for sedimentary marble samples. The
  According to Table 2, the difference between the experimental and the evaluated values reaches up to 20%. The ultrasonic velocity measurements have the highest correlation coefficient of 0.9525 for Sedimentary marble samples. One can see from the Table 3 that the difference between the experimental and the evaluated values for metamorphic marble samples is 20% which is similar to sedimentary marble samples. According to Fig. 9, the highest correlation coefficient is seen in the URA method for metamorphic marble samples. According to Table 4, the difference between the experimental and the evaluated values for travertine marble samples goes up to 50%. This is due to the porosity structure of travertine marble samples. Also all the correlation coefficients are low.
  One can compare three marble groups by their ultrasonic properties. The correlation coefficients of metamorphic marble samples are higher than the others and also travertine marble samples are not suitable because of their porosity structure. Besides, as the mean grain size decreases, the ultrasonic velocity and the rate of heights of successive peaks increase whereas the ultrasonic attenuation coefficient decreases.
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