论文部分内容阅读
本文报导了一种新的Mo—Fc—S原子簇化合物(Et_4N)_4[Mo_3Fe_7S_(13)(PhS)_6]·6CH_3OH的合成与性质。EPR谱的测定结果表明,该原子簇化合物为S≠0的自旋体系。并对乙炔还原为乙烯的催化活性与化合物中Fe/Mo比和Mo的配位环境的关系做了讨论。
This paper reports the synthesis and properties of a novel Mo-Fc-S cluster (Et_4N) _4 [Mo_3Fe_7S_ (13) (PhS) _6] .6CH_3OH. The results of EPR spectra show that the cluster compounds are spin systems with S ≠ 0. The relationship between the catalytic activity of the reduction of acetylene to ethylene and the coordination environment of Fe / Mo and Mo in the compound was also discussed.