论文部分内容阅读
氯化镁被吸附到含有己酮—18—冠—6[DC18C6]的有机相中,分配系数表明对于液—液相3.5M的MgCl2水溶液分离体系的最高值,镁的同位素24Mg,25Mg及26Mg以各的富集因子被富集在该体系中,富集因子24Mg/26Mg的最大值为∈=0.0112。质量数差值为1的同位素富集因子变化取决于水溶相中MgCl2的浓度,DC18C6的同位素识别能力是Kc=1.0016,比分离系数略小是由于Mg2+的水合物与Mg2+的二氯基络合物的交换率Kp=1.0040,奇偶同位素作用被观察,其原因是由质量差所决定,由光学跃迁引起的奇/偶交联对于奇/偶质量数的同位素差异行为提供了合适的解释。
Magnesium chloride was adsorbed to the organic phase containing hexanone-18-crown-6 [DC18C6] and the partition coefficient indicated that the highest isotopes of 24 Mg, 25 Mg and 26 Mg for Mg-C solution at 3.5 M in liquid-liquid phase Each enrichment factor is enriched in the system, and the maximum of enrichment factor 24Mg / 26Mg is ∈ = 0.0112. The variation of isotope enrichment factor with a mass difference of 1 depends on the concentration of MgCl2 in aqueous solution. The isotopic discrimination ability of DC18C6 is Kc = 1.0016, which is slightly lower than the separation factor due to the difference between Mg2 + hydrate and Mg2 + The exchange rate of complex is Kp = 1.0040. The effect of odd and even isotopes is observed due to the poor quality. Odd / even cross-linking caused by optical transition provides suitable for the isotope differential behavior of odd / even mass numbers explanation of.