合成了一种新的含N和S的高分子铑配合物,通过运用红外光谱和XPS电子能谱测试手段,分析表征了配合物存在的NRh配位键和SPh配位键,发现高分子配合物中除了形成配位键的N和S外,还含有未参与配位的N和S;同时发现,这些未配位的N和S在该高分子铑配合物中能发生分子内取代反应,这一独特性质有助于提高该化合物的热稳定性 A new rhodium and rhodium complex containing N and S was synthesized. The NRh coordinate and SPh coordinate of the complex were characterized by IR and XPS. It was found that in addition to N and S which form coordination bonds, the polymer complexes also contain N and S which are not involved in the coordination. At the same time, it is found that these uncoordinated N and S can occur in the polymer rhodium complex Within the substitution reaction, this unique property helps to improve the thermal stability of the compound