Single metal-organic coordination polymers have limited functions as precursors for porous carbon electrode materials. The construction of bimetallic organic coordination polymers can effectively utilize the advantages of each single metal-organic coordination polymer to improve the performance of the derived carbon materials. Herein, High performance nitrogen-doped porous carbon (BCFe–Ni) have been produced by directly carbonizing bimetallic organic coordination polymers formed by 4,4′-bipyridine (BPD) reaction with FeCl3 and NiCl2. The BCFe–Ni exhibits high nitrogen content (12.66 at％), large specific surface area (1049.51 m2 g?1) and hierarchical porous structure, which contributes to an excellent gravimetric specific gravity of 320.5 F g?1 and 108％ of specific capacitance retention after 10000 cycles. The BCFe–Ni assembled symmetrical supercapacitor shows an energy density of 18.3 W h kg?1 at a power density of 350 W kg?1. It is expected that the as-prepared N-doped porous carbon derived from bimetallic-organic coordination polymer is a promising electrode material for high performance energy storage devices.