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利用Ｇａｂｒｉｅｌ反应以聚环硫氯丙烷为起始物合成４种新型的以聚硫醚为主链的伯胺型树脂，研究了树脂的合成条件及吸附性能．这些树脂对贵金属离子有很高的吸附容量，其中每克树脂对Ａｕ（Ⅲ）的吸附容量达到５～７ｍｍｏｌ，对Ａｇ＋的为７～９ｍｍｏｌ；而对贱金属离子吸附甚少，可望用于贵金属离子Ａｕ（Ⅲ）和Ａｇ＋的分离与富集．
In this paper, four kinds of novel polythioether-based primary amine resins were synthesized using polycyclic thiochloropropane as starting materials by Gabriel reaction. The synthesis conditions and adsorption properties of the resins were studied. These resins have a very high adsorption capacity for precious metal ions, of which the adsorption capacity per gram of resin for Au (III) is 5 to 7 mmol and for Ag + 7 to 9 mmol; while the adsorption of base metal ions is very little and is expected to be used in Separation and Enrichment of Au (Ⅲ) and Ag + in Precious Metal Ions.