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2,6-萘二甲酸是一个具有多个配位原子的线性刚性配体,迄今,已报道的2,6-萘二甲酸构筑的配合物有100多个,它们展现了丰富的拓扑结构和潜在的应用价值。本文总结了2,6-萘二甲酸配体的结构特点以及配位模式,并按照金属离子的种类对2,6-萘二甲酸配合物进行分类归纳总结。着重介绍了2,6-萘二甲酸配合物在气体吸附分离、光致发光、磁性及多相催化方面的应用性质,对该类配合物的发展前景进行了展望。
2,6-Naphthalene dicarboxylic acid is a linear rigid ligand with many coordination atoms. So far, more than 100 2,6-naphthalene dicarboxylic acid complexes have been reported, which show a rich topological structure and Potential application value. In this paper, the structural features and coordination modes of 2,6-naphthalene dicarboxylic acid ligands were summarized. The 2,6-naphthalene dicarboxylic acid complexes were classified and classified according to their metal ion species. The application properties of 2,6-naphthalene dicarboxylic acid complex in gas adsorption, photoluminescence, magnetism and heterogeneous catalysis are emphatically introduced. The prospect of the development of these complexes is also discussed.