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以2-氰基-3-[4-(2-氯3-甲基-1-丁酰氧基)」-苯基丙烯酸(A)为质子给体、N-(4-吡啶基亚甲基)-4-烷氧基苯胺(nSSZ)为质子受体,合成了一系列新的氢键复和物.经红外光谱证实了分子间氢键的存在.通过DSC、偏光方法及X射线衍射方法对其液晶行为进行研究.结果表明复合物呈现近品相行为.
(2-chloro-3-methyl-1-butyryloxy) -phenyl acrylic acid (A) as a proton donor and N- (4-pyridylmethylene ) -4-alkyloxyaniline (nSSZ) as a proton acceptor, a series of new hydrogen bond complexes were synthesized. The infrared spectrum confirmed the existence of intermolecular hydrogen bonds. The liquid crystal behavior was studied by DSC, polarized light and X-ray diffraction. The results show that the composite exhibits near-phase behavior.