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在0.2mol/LH2SO4-10%乙醇介质中及紫外光照射条件下磷钼杂多酸光还原为磷钼蓝(λmax=780nm)。据此建立了一个测定0.05~2.0μg/mL磷的光化学分析新方法,并用于试样分析。探讨了光化学反应机理。
The phosphomolybdic heteropolyacid was photo-reduced to phosphomolybdic blue (λmax = 780nm) under the condition of 0.2mol / LH 2 SO 4 -10% ethanol and UV irradiation. A new photochemical method for the determination of phosphorus from 0.05 to 2.0 μg / mL was established and used for sample analysis. The photochemical reaction mechanism was discussed.