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A new energetic dipotassium 3,3?-dinitro-5,5?-bis-1,2,4-triazole-1,1?-diolate [K_2(DNOBT)] was synthesized, and structurally characterized by elemental analysis, IR spectra, 13 C NMR and single-crystal X-ray diffraction. K_2(DNOBT)·2H_2O crystallizes