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A novel organic-inorganic hybrid arsenatomolybdate based on infrequent [AsMo4O14(OH)2]3^- unit,[CuI(phen)2]3[AsMo4O14(oH)2]·3H2O(1,phen =1,10-phenanthroline),has been hydrothermally synthe-sized.This structure was determined by single-crystal X-ray d