Characterization and performance of Pt/SBA-15 for low-temperature SCR of NO by C3H6

来源 :Journal of Environmental Sciences | 被引量 : 0次 | 上传用户:hutuxiaoshenxian
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Pt supported on mesoporous silica SBA-15 was investigated as a catalyst for low temperature selective catalytic reduction(SCR) of NO by C 3 H 6 in the presence of excess oxygen.The prepared catalysts were characterized by means of XRD,BET surface area,TEM,NO-TPD,NO/C 3 H 6-TPO,NH 3-TPD,XPS and 27 Al MAS NMR.The effects of Pt loading amount,O 2 /C 3 H 6 concentration,and incorporation of Al into SBA-15 have been studied.It was found that the removal efficiency increased significantly after Pt loading,but an optimal loading amount was observed.In particular,under an atmosphere of 150 ppm NO,150 ppm C 3 H 6,and 18 vol.% O 2,0.5% Pt/SBA-15 showed remarkably high catalytic performance giving 80.1% NOx reduction and 87.04% C 3 H 6 conversion simultaneously at 140°C.The enhanced SCR activity of Pt/SBA-15 is associated with its outstanding oxidation activities of NO to NO 2 and C 3 H 6 to CO 2 in low temperature range.The research results also suggested that higher concentration of O 2 and higher concentration of C 3 H 6 favored NO removal.The incorporation of Al into SBA-15 improved catalytic performance,which could be ascribed to the enhancement of catalyst surface acidity caused by tetrahedrally coordinated AlO 4.Moreover,the catalysts could be easily reused and possessed good stability. Pt supported on mesoporous silica SBA-15 was investigated as a catalyst for low temperature selective catalytic reduction (SCR) of NO by C 3 H 6 in the presence of excess oxygen. The prepared catalysts were characterized by means of XRD, BET surface area, TEM, NO-TPD, NO / C 3 H 6 -TPO, NH 3-TPD, XPS and 27 Al MAS NMR. These effects of Pt loading amount, O 2 / C 3 H 6 concentration, and incorporation of Al into SBA- 15 have been studied. It was found that the removal efficiency increased significantly after Pt loading, but an optimal loading amount was observed. In particular, under an atmosphere of 150 ppm NO, 150 ppm C 3 H 6, and 18 vol.% O 2,0.5% Pt / SBA-15 showed remarkably high catalytic performance giving 80.1% NOx reduction and 87.04% C3H6 conversion simultaneously at 140 ° C. The enhanced SCR activity of Pt / SBA-15 is associated with its outstanding oxidation activities of NO to NO 2 and C 3 H 6 to CO 2 in low temperature range. The research results also suggest that higher concentration of O 2 and hi gher concentration of C 3 H 6 favored NO removal. The incorporation of Al into SBA-15 improved catalytic performance, which could be ascribed to the enhancement of catalyst surface acidity caused by tetrahedrally coordinated AlO 4.Moreover, the catalysts could be easily reused and possessed good stability.
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