【摘 要】
:
In the present research work,a non-edible oil source Cucumis melo var.agrestis (wild melon) was systematically identified and studied for biodiesel production and its characterization.The extracted oil was 29.1% of total dry seed weight.The free fatty aci
【机 构】
:
Biofuel Laboratory, Department of Plant Sciences, Quaid-i-Azam University, Islamabad, Pakistan;Depar
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In the present research work,a non-edible oil source Cucumis melo var.agrestis (wild melon) was systematically identified and studied for biodiesel production and its characterization.The extracted oil was 29.1% of total dry seed weight.The free fatty acid value of the oil was found to be 0.64%,and the single-step alkaline transesterification method was used for conversion of fatty acids into their respective methyl esters.The maximum conversion efficiency of fatty acids was obtained at 0.4 wt% NaOH (used as catalyst),30% (methanol to oil,v/v) methanol amount,60 ℃ reaction temperature,600-rpm agitation rate and 60-min reaction time.Under these optimal conditions,the conversion efficiency of fatty acid was 92%.However,in the case of KOH as catalyst,the highest conversion (85%) of fatty acids was obtained at 40% methanol to oil ratio,1.28 wt% KOH,60 ℃ reaction temperature,600-rpm agitation rate and 45 min of reaction time.Qualitatively,biodiesel was characterized through Fourier transform infrared spectroscopy (FTIR) and gas chromatography and mass spectroscopy (GC-MS).FTIR results demonstrated a strong peak at 1742 cm-1,showing carbonyl groups (C=O) of methyl esters.However,GC-MS results showed the presence of twelve methyl esters comprised of lauric acid,myristic acid,palmitic acid,non-decanoic acid,hexadecanoic acid,octadecadienoic acid and octadecynoic acid.The fuel properties were found to fall within the range recommended by the international biodiesel standard,i.e.,American Society of Testing Materials (ASTM):flash point of 91 ℃,density of 0.873 kg/L,viscosity of 5.35 cSt,pour point of-13 ℃,cloud point of -10 ℃,total acid number of 0.242 mg KOH/g and sulfur content of 0.0043 wt%.The present work concluded the potential of wild melon seed oil as excellent non-edible source of bioenergy.
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