Synthesis and Nonlinear Optical Property of a Polyphosphazene with High Glass Transition Temperature

来源 :Chinese Chemical Letters | 被引量 : 0次 | 上传用户:tony_zq
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A new polyphosphazene containing binaphtholyl and indole azo chromophores as side chains with high glass transition temperature ( Tg ) was synthesized by a post-functional method. The polymer was well characterized. Its Tg was tested to be 168℃, and the poled film of P2 reveals a resonant d33 value of 20 pm/V by second harmonic generation ( SHG ) measurements. A new polyphosphazene containing binaphtholyl and indole azo chromophores as side chains with high glass transition temperature (Tg) was synthesized by a post-functional method. The polymer was well characterized. Its Tg was tested to be 168 ° C., and the poled film of P2 reveals a resonant d33 value of 20 pm / V by second harmonic generation (SHG) measurements.
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