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鉴于我国目前液化石油气以及乙烯副产碳四馏份分离了丁二烯后的丁烯、丁烷都作燃料烧掉的情况，合理利用这部分资源将其转化为芳烃并用作高辛烷值汽油添加组份或石油化工原料具有重大现实意义。本工作在对丙烷芳构化作了大量工作基础上，采用Ｇａ－ＨＺＳＭ－５催化剂，尤其是以价格低廉的无胺合成的ＺＳＭ－５经改性后制备成Ｇａ－ＨＺＳＭ－５催化剂用正、异丁烷或混合碳四为原料，它具有较高的芳构化活性，芳烃收率可高达６５％。在１０毫升反应装置上反应５０小时后再生，活性可完全恢复。以５０小时为一周期连续１５００小时反应，取得了比较满意的稳定结果。
In view of the current situation of the combustion of butane and butane after the butadiene and butane are separated from the liquefied petroleum gas and the by-product carbon four fraction of ethylene in our country, this part of resource is reasonably utilized to convert it into aromatic hydrocarbon and use it as high octane number Gasoline added components or petrochemical feedstock has great practical significance. In this work, a great deal of work has been done on the propane aromatization. The Ga-HZSM-5 catalyst is used, especially the low cost non-amine synthesized ZSM-5. , Isobutane or mixed carbon four as raw material, it has a high aromatization activity, aromatic yield up to 65%. Regeneration was carried out after reacting for 50 hours on a 10 ml reaction device, and the activity was completely recovered. In a period of 50 hours for 1500 hours of continuous reaction, and achieved a more satisfactory stability.