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亚硝基R盐(NRS)在0.1mol/LKCl溶液中,其电极反应过程为准可逆双电子过程,在有氯化十四烷基吡啶(TPC)存在时,钴与NRS和TPC形成三元钴络物,Co(Ⅲ):NRS:TPC=1:3:6,稳定常数1gβ为:37.80,探讨了其电极反应机理。
The reaction of nitroso R salt (NRS) in 0.1 mol / L KCl solution is a quasi-reversible two-electron process. In the presence of tetrachloropyridinium chloride (TPC), cobalt forms ternary with NRS and TPC Cobalt complex, Co (Ⅲ): NRS: TPC = 1: 3: 6, the stability constant of 1gβ was 37.80, and its electrode reaction mechanism was discussed.