论文部分内容阅读
The title complex [Cu3(TFSSB)2·(H2O)4·4H2O]n (TFSSB=taurine 3-formylsalicylic schiff base) was synthesized by TFSSB and copper(Ⅱ) acetate monohydrate in ethanol solution and the crystal structure was determined by X-ray diffraction method. The crystal belongs to monoclinic system, space group P21 / n,with cell parameters: a=0.927 9(6) nm, b=1.173 0(2) nm, c=1.471(2) nm, β=106.96(2)°, and V=1.531(2) nm3, Z=2, Dc=1.890 g·cm-3, μ=2.291 mm-1, F(000)=882, R1=0.025 9, wR2=0.065 9. The Cu1 is five-coordinate, the Cu2 is four-coordinate. CCDC: 253298.
The title complex [Cu3 (TFSSB) 2 · (H2O) 4 · 4H2O] n (TFSSB = taurine 3-formylsalicylic schiff base) was synthesized by TFSSB and copper (Ⅱ) acetate monohydrate in ethanol solution and the crystal structure was determined by X -ray diffraction method. The crystal belongs to monoclinic system, space group P21 / n, with cell parameters: a = 0.927 9 (6) nm, b = 1.173 0 (2) nm, (000) = 882, R1 = 0.025 9, wR2 = 0.065 (2) nm, Z = 2, Dc = 1.890 g · cm-3 and μ = 2.291 mm- 9. The Cu1 is five-coordinate, the Cu2 is four-coordinate. CCDC: 253298.