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A complex {[Cu(tib)_2(H_2O)_2]·(NO_3)_2}n(1) has been synthesized under N,N-dimethylacetamide(DMA) and water conditions. The structure of complex 1 was characterized by single-crystal X-ray crystallography. It crystallizes in monoclinic, space group P2_1/n with a = 10.6273(7), b = 11.4184(7), c = 13.4215(8) ?, β = 108.290(2)°, V = 1546.38(17) ?~3, Z = 2, F(000) = 798, D_c = 1.667 g/cm~3 and m = 0.786 mm~(-1). Complex 1 exhibits a 3D network due to the existence of O–H···O interaction between coordinated water and nitrate anions. Furthermore, complex 1 has a good catalytic activity for the reduction of 4-nitrophenol in Na BH4 solution.
A complex {[Cu (tib) _2 (H_2O) _2] · (NO_3) _2} n (1) has been synthesized under N, N-dimethylacetamide (DMA) and water conditions. The structure of complex 1 was characterized by single- crystal X-ray crystallography. It crystallizes in monoclinic space group P2_1 / n with a = 10.6273 (7), b = 11.4184 (7), c = 13.4215 (8) °, β = 108.290 (2) °, V = 1546.38 (17) ~ 3, Z = 2, F (000) = 798, D_c = 1.667 g / cm ~ 3 and m = 0.786 mm -1 Complex 1 exhibits a 3D network due to the existence of O- Further, complex 1 has a good catalytic activity for the reduction of 4-nitrophenol in Na BH4 solution.