论文部分内容阅读
聚合型负载金属卟啉化合物是均相催化领域中热门研究课题.通过邻苯二甲酰亚胺等合成了 苯并卟啉锌化合物-中位四苯基苯乙酰胺基苯并卟啉锌、中位四苯基甲基丙烯酰基本并卟啉锌,并 以聚甲基丙烯酸甲酯作为载体,将中位四苯基甲基丙烯酰基苯并卟啉锌进行了负载,采用间接法合 成了甲基丙烯酸甲酯负载的金属卟啉化合物,并对其光谱性能进行了表征.
Polymeric supported metalloporphyrins are a hot research topic in the field of homogeneous catalysis. Zinc tetraphenylphenylacetamidobenzoporphyrin, zinc tetraphenylmethacryl basic zinc porphyrin, were synthesized by phthalimide and the like. Polymethylmethacrylate as carrier, the median tetraphenylmethacrylbenzoporphyrin zinc was loaded, and the methylmethacrylate supported metalloporphyrin compound was synthesized by indirect method, and its spectral properties Characterized.