论文部分内容阅读
一、引言 单线态氧(~1O_2)与含有烯丙基氢原子的烯烃反应,生成过氧化物,同时双键移到α-位:RCH:CH=CH_2+~1O_2真→RCH=CHCH_2OOH这通称为cnc反应。一般用两个机理来说明:
I. INTRODUCTION Singlet oxygen (~ 1O_2) reacts with olefins containing allylic hydrogen atoms to form peroxides, while double bonds move to the α-position: RCH: CH = CH 2 + ~ 1O 2 true → RCH = CHCH 2 OOH This is commonly known as cnc reaction. Generally use two mechanisms to illustrate: