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A new one-dimensional copper coordination polymer chain has been prepared and fully characterized by single-crystal X-ray diffraction,elemental analyses and IR spectroscopy. The compound {[Cu2(C2O4)2(inta)4](inta)}n1 crystallizes in the triclinic system,space group P1,with a=8.4722(5),b=10.9825(6),c=11.6128(6),α=104.8050(10),β=102.5740(10),γ= 109.6890(10)o,V=927.18(9)3,Mr=929.79,Z=1,Dc=1.665 g/cm3,F(000)=475,μ=1.231 mm-1,R=0.0453 and wR=0.1185 for 3290 observed reflections (I > 2σ(I)). Of the compound,the Cu center is octahedrally coordinated with oxalate acting as a tetra-dentate ligand coordinated to the copper atom and each inta serving as a terminal ligand by employing only one N-donor to coordinate with the Cu center. An infinite {Cu2(C2O4)2}∞ chain is formed along the c axis. Furthermore,the 1D chains are held together via extensive hydrogen-bonding interactions to generate a three-dimensional network with 1D channels (ca. 5.491×11.507) where inta molecules are filled.
A new one-dimensional copper coordination polymer chain has been prepared and fully characterized by single-crystal X-ray diffraction, elemental analyzes and IR spectroscopy. The compound {[Cu2 (C2O4) 2 (inta) 4] (inta)} n1 crystallizes in the triclinic system space group P1 with a = 8.4722 (5), b = 10.9825 (6), c = 11.6128 (6) α, α = 104.8050 (10), β = 102.5740 (10), γ = 109.6890 10 = 0, V = 927.18 (9) 3, Mr = 929.79, Z = 1, Dc = 1.665 g / cm3, F (000) = 475, μ = 1.231 mm -1, R = 0.0453 and wR = 0.1185 for 3290 observed reflections (I> 2σ (I)). Of the compound, the Cu center is octahedrally coordinated with oxalate acting as a tetra-dentate ligand coordinated to the copper atom and each inta serves as a terminal ligand by employing only one N- Further, the 1D chains are held together via extensive hydrogen-bonding interactions to generate a three-dimensional network with 1D channels (ca. 5.491 × 11.507) where inta molecules ar e filled.