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用气液色谱法研究了双一(O,O'一二正辛基二硫代磷酸酯)合镍(Ⅱ)与乙酸乙酯加合反应的热力学性质。测定了333.2~363.2K范围内加合反应的平衡常数,用最小二乘法求得反应的△H和△S
The thermodynamic properties of bis (O, O’-dioctylphosphorodithioate) nickel (II) complex with ethyl acetate were studied by gas-liquid chromatography. The equilibrium constants of addition reaction in the range of 333.2-363.2K were determined, and the △ H and △ S