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A new Ni(Ⅱ) cubane-like complex, namely, [Ni(L)(CH_3OH)]_4·(CH_3OH)_2, has been obtained via self-assembly of nickel(Ⅱ) and Schiff base, where the ligand L is a raceme of(R)-2-[(2-hydroxy-1-phenyl-ethylimino)-methyl]-6-methoxy-phenol. X-ray diffracti