Theoretical investigation of the stereoselectivity of some Diels-Alder reactions involving cyclopent

来源 :中国化学快报（英文版） | 被引量 : 0次 | 上传用户：lanrengbuluo

【摘要】

：

The stereoselectivity of some Diels-Alder reactions was investigated by means of ABEEM-oπ model. Combined with local hard-soft and acid-base (HSAB) principle,

【作者】

：

Dong Xia Zhao Zhen Zhen Xu Zho

【机构】

：

College of Chemistry and Chemical Engineering

【出处】

：

中国化学快报（英文版）

【发表日期】

：

2004年期

【关键词】

：

ABEEM-oπ model Diels-Alder reaction Stereoselecfivity Local softness

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The stereoselectivity of some Diels-Alder reactions was investigated by means of ABEEM-oπ model. Combined with local hard-soft and acid-base (HSAB) principle, we made reasonable explanation by calculating local softness of atom and bond regions for the stereoselectivity of four Diels-Alder reactions involving cyclopentadiene.

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Theoretical investigation of the stereoselectivity of some Diels-Alder reactions involving cyclopent

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