Kinetic and Mechanistic Study of Oxidation of Piperazines by Bromamine-T in Acidic Medium

来源 :催化剂现代研究(英文) | 被引量 : 0次 | 上传用户：suqingcsj

【摘要】

：

Oxidations of piperazine, 1-methylpiperazine and 1-ethylpiperazine by bromamine-T (BAT) in buffered acidic medium have been kinetically studied at 303 K. The re

【作者】

：

Chandrashekar &nbsp B. M.

【机构】

：

DepartmentofChemistry,DepartmentofChemistry,DepartmentofChemistry,DepartmentofStudiesinChemistry

【出处】

：

催化剂现代研究(英文)

【发表日期】

：

2013年4期

【关键词】

：

PIPERAZINES OXIDATION KINETICS MECHANISM Bromamine-T BUFFER Piperazines Oxidatio

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Oxidations of piperazine, 1-methylpiperazine and 1-ethylpiperazine by bromamine-T (BAT) in buffered acidic medium have been kinetically studied at 303 K. The reaction shows a first-order dependence of the rate each on [BAT]0 and [piperazine]0, and an inve

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Kinetic and Mechanistic Study of Oxidation of Piperazines by Bromamine-T in Acidic Medium

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