Synergistic Corrosion Inhibition Effect of Molybdate and Phosphate Ions for Anodic Oxidation Film Fo

来源 :武汉理工大学学报(材料科学版)(英文版) | 被引量 : 0次 | 上传用户:2km
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
In order to effectively improve the corrosion resistance of aluminum alloys, anodic oxidation technique was used to generate the oxide film. We investigated the influences of two inorganic corrosion inhibitors (ammonium dihydrogen phosphate and sodium molybdate) on the corrosion resistance of anodic oxidation films on 2024 aluminum alloy, and studied the synergistic effect of two corrosion inhibitors. The corrosion resistance of anodic oxidation film in 3.5wt% NaCl solution was evaluated by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization curves. Results show that, after adding the single ammonium dihydrogen phosphate or sodium molybdate of 0.01 M to oxalic acid electrolyte, inhibition efficiencies of the anodized samples are 10% and 47%, respectively. However, in the presence of two inhibitors with the same concentration of 0.01 M, inhibition efficiency can be as high as 92%. Therefore, we observed the significantly synergistic corrosion inhibition effect of molybdate and phosphate ions for anodic oxidation film formed on 2024 aluminum alloy.
其他文献
Effect of ultrasonic vibration on deformation in micro-blanking was investigated with copper foils of different grain sizes using a developed device. It is found that maximum shearing strength is decreased by ultrasonic vibration, and this effect becomes
For TA15 titanium alloy, slip is the dominant plastic deformation mechanism because of relatively high Al content. In order to reveal the grain-scale stress field and geometrically necessary dislocation (GND) density distribution around the slip traces an
The effects of different Bi contents on the properties of Sn solders were studied. The interfacial reaction and growth behavior of intermetallic compounds (IMCs) layer (η-Cu6Sn5 + e-Cu3Sn) for various soldering time and the influence of Bi addition on the
α-MoO3 nanobelts/carbon nanotubes (CNTs) composites were synthesized by simple hydrothermal method followed by CNTs incorporating, and characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Cyclic voltammogram (CV), electrochemic
The magnetically separable ternary polyetherimide/titanate@Fe3O4 (PTF) photocatalysts of special heterostructure between magnetite (Fe3O4) microspheres and titanates nanosheets modified by polyetherimide (PEI) were successfully fabricated via a simple fac
The combined effects of pre-deformation and pre-aging on the mechanical properties of Al-Cu-Mg alloy with Sc and Zr addition were investigated. It is revealed that the introduction of pre-deformation can enhance the peak-aging strength, as well as tensile
Low melting point alloy is a potential high-temperature heat transfer medium because of the high thermal conductivity, low solidus temperature and wide range of use temperature. Consequently, we investigated the possibility of using Sn–Bi–Zn–Ga alloys as
Functionalized graphene nano-platelets (FGN) were obtained via treating graphene nanoplatelets (GN) with HNO3, and served as adsorbent for the removal of Pb2+ from solutions. We investigated the FGN adsorption capacity for Pb2+ at different initial concen
Hydrothermal treatment has been widely applied in the synthesis of well crystalline calcium silicate hydrate(CSH),such as tobermorite and xonotlite.However,both morphology and crystallinity of CSH are greatly affected by the conditions of hydrothermal tre