We report on white organic light-emitting diodes (WOLEDs) based on polyvinylcarbazole (PVK) doped with 1,1-bis((di-4-tolylamino)phenyl)cyclohexane (TAPC) and perylene,and investigate the luminescence mechanism of the devices.The chromaticity of light emission can be tuned by adjusting the concentration of the dopants.White light with the Commission Intationale de L’Eclairage (CIE) coordinates of (0.33,0.34) is achieved by mixing the yellow electromer emission of TAPC and the blue monomer emission of perylene from the device ITO/PVK:TAPC:perylene (100∶9∶1 in wt.) (100 nm)/tris-(8-hydroxyquinoline aluminum (Alq3) (10 nm)/Al.The device exhibits a maximal luminance of 3727 cd/m2 and a current efficiency of 2 cd/A.