Natural ecosystems provide human society with very important products and services. With the rapid increase in population and the over-exploitation of natural resources, humans are continually enhancing the production of some services at the expense of others. This paper estimates changes in ecosystem services, and the relationship between these services in the Guanzhong-Tianshui Economic Region of China. These ecosystem changes are of great significance to the sustainable development of this economic region. The concept of production possibility frontier(PPF) is applied to evaluate the trade-offs and synergy between carbon sequestration, water yield and soil retention. Three land use strategy scenarios – planning, exploitation and protection – are applied to evaluate potential changes in ecosystem services. This study reveals noticeable trade-offs between carbon sequestration, soil retention and water yield, with synergy between carbon sequestration and soil retention. There are synergies between carbon sequestration, water yield and soil retention in the three scenarios. The protection scenario is the most favourable land use strategy for regulating ecosystem service capacity. This scenario results in the highest carbon sequestration, water yield and soil retention. The results could have implications for natural capital and ecosystem services planning, management and land use decision-making. With the rapid increase in population and the over-exploitation of natural resources, humans are continually enhancing the production of some services at the expense of others. This paper estimates changes in ecosystem services, and the relationship between these services in the Guanzhong-Tianshui Economic Region of China. Both concept of production potential frontier (PPF) is applied to evaluate the trade-offs and Three land use strategy scenarios - planning, exploitation and protection - are applied to evaluate potential changes in ecosystem services. This study reveals noticeable trade-offs between carbon sequestration, soil retention and water yield, with synergy between carbon sequestration and soil retention. There are s The protection results is the most favourable land use strategy for regulating ecosystem service capacity. This scenario results in the highest carbon sequestration, water yield and soil retention. The results could have have implications for natural capital and ecosystem services planning, management and land use decision-making.