Angew.Chem.Int.Ed.2017,56,4734~4738有机氟化合物因其在制药、农药、材料科学领域的广泛应用而受到人们的关注,利用含氟碳自由基实现三氟甲基化和二氟烷基化的方法已经有了显著发展,但是单氟代碳自由基烷基化方法却鲜有报道.此外分子内脱氢偶联反 Angew.Chem.Int.Ed.2017,56,4734 ~ 4738 Organofluorine compounds have drawn much attention due to their wide application in the field of pharmaceuticals, pesticides and materials science, and the use of fluorine-containing carbon radicals for trifluoromethylation and The method of difluoroalkylation has evolved significantly, but the monofluorocarbon radical alkylation has rarely been reported.In addition, the intramolecular dehydrogenation coupling