Cation-induced assembly of Zn(II), Cd(II) and Hg(II) coordination complexes and DFT calculations to

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二新协作聚合物[ZnLI2 ](1 ) 并且[CdLI2 ](2 )(L:3,6-di-(1,2,4-triazole-1-yl )-N-hexylcarbazole) 被综合,他们的水晶结构被单个水晶的 X 光检查衍射技术决定。建筑群两个都沿着 2 1 螺丝钉轴与螺旋状的链被构造。协作契约, C -- 嗨弱相互作用并且 - 相互作用在构造他们的 3D 或 2D 框架起重要作用。二不同 DFT 计算为在三不同协作聚合物的螺旋状的链之间的弱相互作用被执行([ZnLI2 ] ,[CdLI2 ] 并且报导[Hg
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