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Cl+H_2(包括同位素D_2和DH)→HCl+H反应是重-轻-轻(H-L-L’)质量组合体系的样板之一.实验上发现,当H_2的振动量子数由0激发到1,300K下的反应速度常数司以增加两个数量级以上,这种反应物分子的振动增强效应引起了理论化学家的兴趣.Persky
Cl + H_2 (including isotopes of D_2 and DH) → HCl + H is one of the samples of the combined mass system of heavy and light-light (HL-L ’). Experimentally found that when the vibrational quantum number of H_2 is excited from 0 to 1,300 K under the reaction rate constant to increase more than two orders of magnitude, the reactant molecules enhance the effect of vibration caused the interest of theoretical chemists .Persky