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A novel 3-D inorganic bimetallic compound Ag2Mo2O7 has been hydrothermally synthesized and structurally characterized by X-ray diffraction. The compound crystallizes in mono- clinic, space group P21/c with a = 6.1274(3), b = 13.1836(6), c = 7.8780(3) ?, β = 110.673(3)°, V = 595.42(5) ?3, Z = 4, Mr = 519.62, Dc = 5.797 g/cm3, F(000) = 936, μ(MoKα) = 10.579 mm?1, F(000) = 936, the final R = 0.0204 and wR = 0.0477 for 1268 observed reflections with I > 2σ(I). In the title compound, the [Mo4O16]n 8n?chains are linked through O?Ag?O bridging bonds to form a 3D network. It represents an unprecedented linking mode between the isopolyoxomolybdate chain and the transition metal oxide cluster. IR, TGA and fluorescence properties of the title compound are also studied.
A novel 3-D inorganic bimetallic compound Ag2Mo2O7 has been hydrothermally synthesized and structurally characterized by X-ray diffraction. The compound crystallizes in mono- clinic, space group P21 / c with a = 6.1274 (3), b = 13.1836 (5) = 3, Z = 4, Mr = 519.62, Dc = 5.797 g / cm3, F (000) = 936, μ ) = 10.579 mm? 1, F (000) = 936, the final R = 0.0204 and wR = 0.0477 for 1268 observed reflections with I> 2σ (I). In the title compound, the [Mo4O16] n8n? through O? Ag? O bridging bonds to form a 3D network. It represents an economic linking mode between the isopolyoxomolybdate chain and the transition metal oxide cluster. IR, TGA and fluorescence properties of the title compound are also studied.