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从秦岭大黄RheumqinlingenseY.K.Yang,D.K.ZhangetJ.K.Wu根茎的乙醇溶性部分分得10个化合物,经光谱学鉴定,它们的结构分别为大黄酚(chrysophanol,Ⅰ)、大黄素甲醚(physcione,Ⅱ)、芦荟大黄素(aloe-emodin,Ⅲ)、大黄素(emodin,Ⅳ)、大黄酚8-O-β-D-吡喃葡萄糖苷(chrysophanol8-O-β-D-glucopyranoside,Ⅴ)、大黄素甲醚8-O-β-D-吡喃葡萄糖苷(physcione8-O-β-D-glucopyranoside,Ⅵ)、芦荟大黄素8-O-β-D-吡喃葡萄糖苷(aloe-emodin8-O-β-D-glucopyranoside,Ⅶ)大黄素8-O-β-D-吡喃葡萄糖苷(emodin8-O-β-D-glucopyranoside,Ⅷ)、大黄酸(rhein,Ⅸ)和大黄酚8-O-β-D-(6′-O-丙二酸单酰基)吡喃葡萄糖苷[chrysophanol8-O-β-D-(6′-O-malonyl)glucopyranoside,Ⅹ]。其中化合物Ⅹ系新化合物,Ⅵ和Ⅷ为首次从秦岭大黄中分得。
From the ethanol-soluble fraction of Rheumqinlingense Y.K.Yang and DKZhangetJ.K.Wu of rhubarb from Qinling Mountains, 10 compounds were identified. Their structures were identified by spectroscopic analysis as chrysophanol (I) and physcione. , II), aloe-emodin (III), emodin (IV), chrysophanol 8-O-β-D-glucopyranoside (V) , physcione8-O-β-D-glucopyranoside (VI), aloe-emodin-8-O-β-D-glucopyranoside (aloe-emodin8) -O-β-D-glucopyranoside, VII) Emodin 8-O-β-D-glucopyranoside (VIII), rhein (IX), and chrysophanol 8 -O-β-D-(6’-O-malonyl)glucopyranoside [chrysophanol8-O-β-D-(6’-O-malonyl) glucopyranoside, X]. Among them, Compound X is a new compound, and VI and VIII are firstly obtained from the rhizosphere of Qinling.